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PIDA (polymer) : ウィキペディア英語版 | PIDA (polymer)
|Section8= }} PIDA, or poly(diiododiacetylene), is an organic polymer that has a polydiacetylene backbone. It is one of the simplest polydiacetylenes that has been synthesized, having only iodine atoms as side chains. It is created by 1,4 topochemical polymerization of diiodobutadiyne. It has many implications in the field of polymer chemistry as it can be viewed as a precursor to other polydiacetylenes by replacing iodine atoms with other side chains using organic synthesis, or as an iodinated form of the carbon allotrope carbyne. ==Structure== The backone of PIDA is highly conjugated and allows for the formation of an extended pi system along the length of the polymer. This property of PIDA allows it to transport electricity and act as a molecular wire or an organic semiconductor. Considering PIDA's backbone and the fact that Iodine atoms can easily undergo elimination, it is conceivable that PIDA can be subjected to full reductive deiodination in the precsence of a lewis base, such as pyrrolidine〔 to yield carbyne.
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